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Year 11 / Properties and structure of materials

Structure explains what a material does.

In ionic solids, ions cannot move freely, but molten or dissolved ions can carry current. Metals conduct through delocalised electrons and can deform as atomic layers shift. Small covalent molecules usually melt more easily than extended covalent networks. Diamond is a rigid covalent network; graphite has layers and mobile electrons along them.

A pure substance has fixed composition and characteristic properties; a mixture can vary in composition. Homogeneous mixtures are uniform at the observation scale, whereas heterogeneous mixtures have distinguishable regions. Hydrocarbons also differ in bonding: alkenes contain C=C bonds that can undergo addition, while benzene has delocalised bonding.

INTERACTIVE MODEL

Mobile charge carriers

READ THE GRAPH

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A counting model, not a conductivity prediction. Solid ionic lattices have negligible ion mobility; molten ions and metallic electrons can move.

Mobile charged particles / relative units013.1326.2539.3852.50255075100Total charged particles / relative units
Mobile charged particles / relative units

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View plotted data as a table
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SeriesTotal charged particles / relative unitsMobile charged particles / relative units
Mobile charged particles / relative units00
Mobile charged particles / relative units1.666670.833333
Mobile charged particles / relative units3.333331.66667
Mobile charged particles / relative units52.5
Mobile charged particles / relative units6.666673.33333
Mobile charged particles / relative units8.333334.16667
Mobile charged particles / relative units105
Mobile charged particles / relative units11.66675.83333
Mobile charged particles / relative units13.33336.66667
Mobile charged particles / relative units157.5
Mobile charged particles / relative units16.66678.33333
Mobile charged particles / relative units18.33339.16667
Mobile charged particles / relative units2010
Mobile charged particles / relative units21.666710.8333
Mobile charged particles / relative units23.333311.6667
Mobile charged particles / relative units2512.5
Mobile charged particles / relative units26.666713.3333
Mobile charged particles / relative units28.333314.1667
Mobile charged particles / relative units3015
Mobile charged particles / relative units31.666715.8333
Mobile charged particles / relative units33.333316.6667
Mobile charged particles / relative units3517.5
Mobile charged particles / relative units36.666718.3333
Mobile charged particles / relative units38.333319.1667
Mobile charged particles / relative units4020
Mobile charged particles / relative units41.666720.8333
Mobile charged particles / relative units43.333321.6667
Mobile charged particles / relative units4522.5
Mobile charged particles / relative units46.666723.3333
Mobile charged particles / relative units48.333324.1667
Mobile charged particles / relative units5025
Mobile charged particles / relative units51.666725.8333
Mobile charged particles / relative units53.333326.6667
Mobile charged particles / relative units5527.5
Mobile charged particles / relative units56.666728.3333
Mobile charged particles / relative units58.333329.1667
Mobile charged particles / relative units6030
Mobile charged particles / relative units61.666730.8333
Mobile charged particles / relative units63.333331.6667
Mobile charged particles / relative units6532.5
Mobile charged particles / relative units66.666733.3333
Mobile charged particles / relative units68.333334.1667
Mobile charged particles / relative units7035
Mobile charged particles / relative units71.666735.8333
Mobile charged particles / relative units73.333336.6667
Mobile charged particles / relative units7537.5
Mobile charged particles / relative units76.666738.3333
Mobile charged particles / relative units78.333339.1667
Mobile charged particles / relative units8040
Mobile charged particles / relative units81.666740.8333
Mobile charged particles / relative units83.333341.6667
Mobile charged particles / relative units8542.5
Mobile charged particles / relative units86.666743.3333
Mobile charged particles / relative units88.333344.1667
Mobile charged particles / relative units9045
Mobile charged particles / relative units91.666745.8333
Mobile charged particles / relative units93.333346.6667
Mobile charged particles / relative units9547.5
Mobile charged particles / relative units96.666748.3333
Mobile charged particles / relative units98.333349.1667
Mobile charged particles / relative units10050
Mobile charged particles / relative units: 0

Explore: Change the fraction of mobile charge carriers. Relate the limits to a solid ionic lattice and a molten ionic sample.

structuremobile charges and attractionsproperties\text{structure}\longrightarrow\text{mobile charges and attractions}\longrightarrow\text{properties}
WORKED EXAMPLE

Explain why solid sodium chloride does not conduct but molten sodium chloride does.

  1. Both contain ions, but the solid lattice fixes their positions.
  2. Melting allows charged ions to move and carry current.
Assumed knowledge

Ions, electrons and covalent bonds.

Learning checkpoints & sourceYOUR LEARNING CHECKPOINT
  • Compare ionic, metallic, molecular and network structures.
  • Distinguish pure substances, mixtures and carbon allotropes.
QCAA Chemistry · Unit 1 · Properties and structure of materials
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