weirdfacts
Year 12 / Quantum theory

Only some energy steps fit.

Discrete atomic energies produce line spectra. Emission occurs when an electron moves to a lower energy state and a photon carries the energy difference. Absorption requires a matching available upward energy step. The Bohr model describes hydrogen energy levels but is not a general model for many-electron atoms.

The standing-wave condition around a Bohr orbit is nλ = 2πr, giving mvr = nh/(2π). Matter has de Broglie wavelength h/p. Electron diffraction supports wave behaviour of matter, while localised detection and the photoelectric effect demonstrate particle-like behaviour.

INTERACTIVE MODEL

Hydrogen energy levels

READ THE GRAPH

Explore the relationship

Allowed initial and final levels are integers. The continuous line is only a guide between allowed transitions.

Photon energy magnitude / eV00.83671.6732.513.34745678Initial principal level
Photon energy magnitude / eV

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View plotted data as a table
Explore the relationship
SeriesInitial principal levelPhoton energy magnitude / eV
Photon energy magnitude / eV42.55
Photon energy magnitude / eV4.066672.57764
Photon energy magnitude / eV4.133332.60395
Photon energy magnitude / eV4.22.62902
Photon energy magnitude / eV4.266672.65293
Photon energy magnitude / eV4.333332.67574
Photon energy magnitude / eV4.42.69752
Photon energy magnitude / eV4.466672.71833
Photon energy magnitude / eV4.533332.73824
Photon energy magnitude / eV4.62.75728
Photon energy magnitude / eV4.666672.77551
Photon energy magnitude / eV4.733332.79298
Photon energy magnitude / eV4.82.80972
Photon energy magnitude / eV4.866672.82578
Photon energy magnitude / eV4.933332.8412
Photon energy magnitude / eV52.856
Photon energy magnitude / eV5.066672.87022
Photon energy magnitude / eV5.133332.88389
Photon energy magnitude / eV5.22.89704
Photon energy magnitude / eV5.266672.90969
Photon energy magnitude / eV5.333332.92188
Photon energy magnitude / eV5.42.93361
Photon energy magnitude / eV5.466672.94491
Photon energy magnitude / eV5.533332.95581
Photon energy magnitude / eV5.62.96633
Photon energy magnitude / eV5.666672.97647
Photon energy magnitude / eV5.733332.98626
Photon energy magnitude / eV5.82.99572
Photon energy magnitude / eV5.866673.00486
Photon energy magnitude / eV5.933333.01369
Photon energy magnitude / eV63.02222
Photon energy magnitude / eV6.066673.03048
Photon energy magnitude / eV6.133333.03847
Photon energy magnitude / eV6.23.0462
Photon energy magnitude / eV6.266673.05369
Photon energy magnitude / eV6.333333.06094
Photon energy magnitude / eV6.43.06797
Photon energy magnitude / eV6.466673.07478
Photon energy magnitude / eV6.533333.08138
Photon energy magnitude / eV6.63.08779
Photon energy magnitude / eV6.666673.094
Photon energy magnitude / eV6.733333.10003
Photon energy magnitude / eV6.83.10588
Photon energy magnitude / eV6.866673.11157
Photon energy magnitude / eV6.933333.11709
Photon energy magnitude / eV73.12245
Photon energy magnitude / eV7.066673.12766
Photon energy magnitude / eV7.133333.13273
Photon energy magnitude / eV7.23.13765
Photon energy magnitude / eV7.266673.14245
Photon energy magnitude / eV7.333333.14711
Photon energy magnitude / eV7.43.15164
Photon energy magnitude / eV7.466673.15606
Photon energy magnitude / eV7.533333.16036
Photon energy magnitude / eV7.63.16454
Photon energy magnitude / eV7.666673.16862
Photon energy magnitude / eV7.733333.17259
Photon energy magnitude / eV7.83.17646
Photon energy magnitude / eV7.866673.18024
Photon energy magnitude / eV7.933333.18391
Photon energy magnitude / eV83.1875
Photon energy magnitude / eV: 2.55

Explore: Compare transitions to different final levels. Which emits the highest-energy photon?

Eγ=EiEfλ=hp1λ=R(1nf21ni2)E_{\gamma}=E_i-E_f\quad\lambda=\frac hp\quad\frac1\lambda=R\left(\frac1{n_f^2}-\frac1{n_i^2}\right)
WORKED EXAMPLE

An electron drops from −1.5 eV to −3.4 eV.

  1. Photon energy = (−1.5) − (−3.4) = 1.9 eV.
  2. A positive photon energy is released.
Assumed knowledge

Energy conservation and negative energy levels.

Learning checkpoints & sourceYOUR LEARNING CHECKPOINT
  • Connect atomic levels with absorption and emission spectra.
  • Use de Broglie wavelength and the hydrogen model.
QCAA Physics · Unit 4 · Quantum theory
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