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Year 12 / Functional groups and formulas

Read a molecule’s signature.

Functional groups help predict characteristic reactions: hydroxyl in alcohols, carboxyl in carboxylic acids, carbonyl in aldehydes and ketones, and ester, amino and amide groups in their respective classes. Haloalkanes contain a carbon–halogen bond.

Alkanes contain only C–C single bonds; alkenes contain C=C and alkynes C≡C. Members of a homologous series share a functional group and a general pattern, with successive members differing by CH₂.

A molecular formula gives actual atom counts; an empirical formula gives their simplest ratio; a structural formula shows connections. C₂H₆O can represent ethanol or dimethyl ether, so a molecular formula alone does not determine structure.

INTERACTIVE MODEL

Spot the functional group

CH₃CH₂OHEthanol
Hydroxyl → alcohol · C₂H₆O

Condensed structural diagrams. Bonds show connectivity, not measured bond angles. Compare the molecular formula with the arrangement of atoms.

CH₃CH₂OH: alcohol CH₃COOH: carboxylic acid CH₃COOCH₃: ester
Assumed knowledge

Carbon forms four bonds in these neutral structures; oxygen two.

Learning checkpoints & sourceYOUR SYLLABUS CHECKPOINT
  • Recognise organic classes and functional groups.
  • Distinguish molecular, empirical and structural formulas.
  • Identify saturated and unsaturated compounds.
QCAA Chemistry 2025 v1.3 · p. 39
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