weirdfacts

For aA + bB ⇌ cC + dD, concentrations are raised to their stoichiometric coefficients. Pure solids and pure liquids are omitted from the expression. K uses equilibrium concentrations; Q uses the concentrations at the moment being considered.

If Q < K, there is relatively too little product and the net reaction proceeds forward. If Q > K, it proceeds in reverse. If Q = K, the mixture is at equilibrium. A large K favours products; it says nothing by itself about speed.

For concentration calculations, first account for the reaction stoichiometry. An ICE table lists initial, change and equilibrium values. If a small-x approximation is used because K is small, state it and check that the neglected change is acceptably small.

INTERACTIVE MODEL

A balance that keeps moving

Orange: A · Blue: B · Particles continue to move00.250.50.751TimeConcentrationAB
[A] = 0.344 M · [B] = 0.656 M

Illustrative A ⇌ B model in a closed system; total concentration 1.00 mol L⁻¹. Ratio K = [B]/[A]. Not a model of any particular industrial reaction.

H₂(g) + I₂(g) ⇌ 2HI(g) Kc = [HI]² / ([H₂][I₂])
Assumed knowledge

Substitution, powers and square roots.

Learning checkpoints & sourceYOUR SYLLABUS CHECKPOINT
  • Construct Kc expressions, including heterogeneous systems.
  • Compare Q and K to predict a net reaction.
  • Calculate equilibrium concentrations.
QCAA Chemistry 2025 v1.3 · p. 32
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