Which way will it go?
For aA + bB ⇌ cC + dD, concentrations are raised to their stoichiometric coefficients. Pure solids and pure liquids are omitted from the expression. K uses equilibrium concentrations; Q uses the concentrations at the moment being considered.
If Q < K, there is relatively too little product and the net reaction proceeds forward. If Q > K, it proceeds in reverse. If Q = K, the mixture is at equilibrium. A large K favours products; it says nothing by itself about speed.
For concentration calculations, first account for the reaction stoichiometry. An ICE table lists initial, change and equilibrium values. If a small-x approximation is used because K is small, state it and check that the neglected change is acceptably small.
A balance that keeps moving
Illustrative A ⇌ B model in a closed system; total concentration 1.00 mol L⁻¹. Ratio K = [B]/[A]. Not a model of any particular industrial reaction.
Assumed knowledge
Substitution, powers and square roots.
Learning checkpoints & source
YOUR SYLLABUS CHECKPOINT- Construct Kc expressions, including heterogeneous systems.
- Compare Q and K to predict a net reaction.
- Calculate equilibrium concentrations.